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Because of its robustness and chemical inertness FotoSense is especially attractive for use with process analysers and ensures trouble free unattended operation.

 

Determination of water hardness

A very common application of the FotoSense is in the determination of the calcium and total hardness of city water. The methodology is very straightforward. The sample is made alkaline with an ammonium chloride / ammonia buffer and a small amount of eriochrome black T (EBT) solution added (*). A FotoSense 630 (red) is used to follow the titration with EDTA. At the end-point there is a sharp change from red to blue and a very distinct step change of the sensor output.
The graphic shows typical titration curves using two different amounts of EBT indicator. This photometric titration is a very stable and unproblematic in contrast to a potentiometric measurement with for example a calcium ion selective electrode which drifts and looses sensitivity in a matter of a few months.
 

 

A FotoSense is mounted in a process analyser for the determination of water hardness.

 
 
 
         
     

Chemro AG, Haldenstrasse 9, CH-8185 Winkel, info@chemro.com